Improving Interfaces in All-Solid-State Supercapacitors Using Polymer-Added Activated Carbon Electrodes

نویسندگان

چکیده

Solvent-free all-solid-state supercapacitors have recently received attention. Despite their highly specific capacitance, they suffer issues related to the solid–solid interface that degrade performance during prolonged cycling. Here, we propose a novel strategy for improving electrode–electrolyte by introducing small amount of polymer into activated carbon-based electrode. An electrode composition 80AC:8SA:7AB:5[PEO0.95 (LiClO4)0.05]—where AC, SA, and AB stand carbon, sodium alginate binder, acetylene black, respectively—is optimized. A composite membrane—viz., PEO-LiClO4 reinforced with 38 wt% NASICON structured nano crystallites Li1.3Al0.3Ti1.7(PO4)3—is used as solid electrolyte. Incorporating salt-in-polymer (95PEO-5 LiClO4) in matrix leads smooth formation, thereby parameters (ASSCs). typical supercapacitor polymer-incorporated exhibits capacitance ~102 Fg?1 at discharge current 1.5 Ag?1 an operating voltage 2 V near room temperature. These ASSCs also exhibit relatively better galvanostatic charge–discharge cycling, coulombic efficiency, energy, power comparison those based on conventional carbon.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

All-solid-state high performance asymmetric supercapacitors based on novel MnS nanocrystal and activated carbon materials

All-solid-state high-performance asymmetric supercapacitors (ASCs) are fabricated using γ-MnS as positive electrode and porous eggplant derived activated carbon (EDAC) as negative electrode with saturated potassium hydroxide agar gel as the solid electrolyte. The laminar wurtzite nanostructure of γ-MnS facilitates the insertion of hydroxyl ions into the interlayer space, and the manganese sulfi...

متن کامل

Stretchable, Weavable Coiled Carbon Nanotube/MnO2/Polymer Fiber Solid-State Supercapacitors

Fiber and yarn supercapacitors that are elastomerically deformable without performance loss are sought for such applications as power sources for wearable electronics, micro-devices, and implantable medical devices. Previously reported yarn and fiber supercapacitors are expensive to fabricate, difficult to upscale, or non-stretchable, which limits possible use. The elastomeric electrodes of the...

متن کامل

Nitrogenated porous carbon electrodes for supercapacitors

Nitrogenated porous carbon materials, made by coating the pore surface with nitrogen functional groups from the pyrolysis of hexamine, were characterized and tested for supercapacitor applications. From X-ray photoelectron spectroscopy, the nitrogen content of the nitrogenated carbon sample was found to be 14 wt%. Electrochemical properties from potentiostatic and galvanostatic measurements, an...

متن کامل

Activated Carbon Produced from Sasol-lurgi Gasifier Pitch and Its Application as Electrodes in Supercapacitors

A pyrolysis product derived from SASOL-Lurgi gasifier pitch was activated using different proportions of KOH. The increase of the amount of KOH used for activation caused the activation degree of the carbons to increase very significantly. The activated carbons obtained using lower amounts of KOH were mainly microporous, while the amount of mesopores developed in the samples progressively incre...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Batteries

سال: 2023

ISSN: ['2313-0105']

DOI: https://doi.org/10.3390/batteries9020081